Mineral Factbook

Hopeite

Zn3(PO4)2·4H2OIMA symbol: Hopgrandfathered

Hopeite is a phosphate, arsenate, or vanadate mineral with the formula Zn3(PO4)2·4H2O, crystallizing in the orthorhombic system. It has a Mohs hardness of 2.5-3, typically white, brown, gray or red in color, with a pearly or vitreous luster, a specific gravity of 3.338. Its streak is white.

Photos

Hopeite specimen photo
Didier Descouens · CC BY-SA 3.0 · Commons
Hopeite specimen photo
Aangelo · CC BY-SA 3.0 · Commons
Hopeite specimen photo
Eric Polk · CC BY-SA 4.0 · Commons
Hopeite specimen photo
Robert M. Lavinsky · CC BY-SA 3.0 · Commons

Crystallography

Crystal systemorthorhombic crystal systemWikidata (CC0)
Space groupP b n m
Cell (Å, °)a = 5.0135, b = 10.6044, c = 18.2828; α = 90, β = 90, γ = 90
Cell volume972.008 ų, Z = 4
Axial ratios0.4728:1:1.7241calculated from COD 9014818
Source structureCOD 9014818 (Chemistry - A European Journal, 2004) — 1 of 6 structures

Powder X-ray diffraction (calculated)

2θ (degrees, Cu Kα1)I/I₀ (max 100)
d (Å)2.8499.1414.5713.3844.3993.462
I/I₀10059.949.147.539.231.2

xrd-v1: CuKa1 1.5406A, 2theta 5-90, top10, Imax=100, no DW/PO. Computed from COD 9014818; idealized occupancies, no preferred orientation.

Physical properties

Density (calculated)3.131 g/cm³calculated from COD 9014818
Hardness (Mohs)
2.5-3single sourceDana, System of Mineralogy, 6th ed. (1892)
Specific gravity
3.338 g/cm3single sourceFord, Dana's Textbook of Mineralogy, 3rd ed. (1922)
Color
brown, gray, red, whitesingle sourceDana, System of Mineralogy, 6th ed. (1892)
Streak
whitesingle sourceWikidata (CC0)
whitesingle sourceDana, System of Mineralogy, 6th ed. (1892)
Luster
pearly, vitreoussingle sourceDana, System of Mineralogy, 6th ed. (1892)

Chemistry (calculated)

Molecular weight458.23 g/molcalculated from the IMA formula
Composition (wt%)Zn 42.82%, P 13.52%, O 41.9%, H 1.76%

Classification

Nickel-Strunz (10th)8.CA.30Wikidata (CC0)
Nickel-Strunz (9th)8.CA.30Wikidata (CC0)