Mineral Factbook

Libethenite

Cu2(PO4)(OH)IMA symbol: Libgrandfathered

Libethenite is a phosphate, arsenate, or vanadate mineral with the formula Cu2(PO4)(OH), crystallizing in the orthorhombic system. It has a Mohs hardness of 4, typically green in color, with a resinous luster, a specific gravity of 3.6-3.8. Its streak is green.

Photos

Libethenite specimen photo
Didier Descouens · CC BY-SA 3.0 · Commons
Libethenite specimen photo
Tõnis Saadre · CC BY-SA 4.0 · Commons
Libethenite specimen photo
Mai Seppel · CC BY-SA 4.0 · Commons
Libethenite specimen photo
Mai Seppel · CC BY-SA 4.0 · Commons

Crystallography

Crystal systemorthorhombic crystal systemWikidata (CC0)
Space groupP n n m
Cell (Å, °)a = 8.062, b = 8.384, c = 5.881; α = 90, β = 90, γ = 90
Cell volume397.507 ų, Z = 4
Axial ratios0.9616:1:0.7015calculated from COD 9004131
Source structureCOD 9004131 (The Canadian Mineralogist, 1978) — 1 of 5 structures

Powder X-ray diffraction (calculated)

2θ (degrees, Cu Kα1)I/I₀ (max 100)
d (Å)4.8155.8112.6242.9064.7513.719
I/I₀1009795.293.478.955.5

xrd-v1: CuKa1 1.5406A, 2theta 5-90, top10, Imax=100, no DW/PO. Computed from COD 9004131; idealized occupancies, no preferred orientation.

Physical properties

Density (calculated)3.995 g/cm³calculated from COD 9004131
Hardness (Mohs)
4single sourceWikidata (CC0)
4single sourceDana, System of Mineralogy, 6th ed. (1892)
Specific gravity
3.6-3.8 g/cm3single sourceDana, System of Mineralogy, 6th ed. (1892)
Color
greensingle sourceDana, System of Mineralogy, 6th ed. (1892)
Streak
greensingle sourceDana, System of Mineralogy, 6th ed. (1892)
Luster
resinoussingle sourceDana, System of Mineralogy, 6th ed. (1892)

Chemistry (calculated)

Molecular weight239.07 g/molcalculated from the IMA formula
Composition (wt%)Cu 53.16%, P 12.96%, O 33.46%, H 0.42%

Classification

Nickel-Strunz (10th)8.BB.30Wikidata (CC0)
Nickel-Strunz (9th)8.BB.30Wikidata (CC0)
Dana (8th)41.6.6.2Wikidata (CC0)