Shigaite Mn6 Al3 (OH)18 [Na(H2 O)6 ](SO4 )2 ·6 H2 O IMA symbol: Sga approved
Shigaite is a sulfate mineral with the formula Mn6Al3(OH)18[Na(H2O)6](SO4)2·6H2O, crystallizing in the trigonal system. It has a calculated density of 2.207 g/cm3.
Crystallography Crystal system trigonal crystal systemWikidata (CC0) Space group R -3 :H Cell (Å, °) a = 9.512, b = 9.512, c = 33.074; α = 90, β = 90, γ = 120 Cell volume 2591.56 ų, Z = 3 Axial ratios 1.0000:1:3.4771calculated from COD 9004406 Source structure COD 9004406 (The Canadian Mineralogist, 1996)
Powder X-ray diffraction (calculated) 2θ (degrees, Cu Kα1) I/I₀ (max 100) d (Å) 11.025 5.512 3.675 2.458 1.945 2.2 I/I₀ 100 29.1 23.1 23.1 16.3 14.9
xrd-v1: CuKa1 1.5406A, 2theta 5-90, top10, Imax=100, no DW/PO. Computed from COD 9004406; idealized occupancies, no preferred orientation.
Physical properties Density (calculated) 2.207 g/cm³calculated from COD 9004406
Chemistry (calculated) Molecular weight 1148.0 g/molcalculated from the IMA formula Composition (wt%) Mn 28.71%, Al 7.05%, O 52.96%, H 3.69%, Na 2%, S 5.59%
Classification Nickel-Strunz (10th) 7.DD.35Wikidata (CC0) Nickel-Strunz (9th) 7.DD.35Wikidata (CC0)